TY  - GEN
TY  - GEN
T1  - State-to-State Dynamical Research in the F+H2 Reaction System
T2  - Springer Theses, Recognizing Outstanding Ph.D. Research,
A1  - Ren, Zefeng.
LA  - English
PP  - Berlin, Heidelberg
PB  - Springer Berlin Heidelberg : Imprint: Springer
YR  - 2014
ED  - 1st ed. 2014.
UL  - http://discoverylib.upm.edu.my/discovery/Record/978-3-642-39756-1
AB  - This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy. .
OP  - 77
CN  - QD450-882
SN  - 9783642397561
KW  - Physical chemistry.
KW  - Atomic structure  .
KW  - Molecular structure .
KW  - Chemistry, Physical and theoretical.
KW  - Spectroscopy.
KW  - Physical Chemistry.
KW  - Atomic/Molecular Structure and Spectra.
KW  - Theoretical and Computational Chemistry.
KW  - Spectroscopy/Spectrometry.
ER  -