Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation

Photocatalytic degradation of p-cresol was carried out using ZnO under UV irradiation. The amount of photocatalyst, concentration of p-cresol and pH were studied as variables. The residual concentration and mineralization of p-cresol was monitored using a UV-visible spectrophotometer and total organ...

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Hoofdauteurs: Abdollahi, Yadollah, Abdullah, Abdul Halim, Zainal, Zulkarnain, Yusof, Nor Azah
Formaat: Artikel
Taal:English
Gepubliceerd in: MDPI 2012
Online toegang:http://psasir.upm.edu.my/id/eprint/25222/1/Photocatalytic%20degradation%20of%20p.pdf
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spelling oai:psasir.upm.edu.my:25222 http://psasir.upm.edu.my/id/eprint/25222/ Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation Abdollahi, Yadollah Abdullah, Abdul Halim Zainal, Zulkarnain Yusof, Nor Azah Photocatalytic degradation of p-cresol was carried out using ZnO under UV irradiation. The amount of photocatalyst, concentration of p-cresol and pH were studied as variables. The residual concentration and mineralization of p-cresol was monitored using a UV-visible spectrophotometer and total organic carbon (TOC) analyzer, respectively. The intermediates were detected by ultra high pressure liquid chromatography (UPLC). The highest photodegradation of p-cresol was observed at 2.5 g/L of ZnO and 100 ppm of pcresol. P-cresol photocatalytic degradation was favorable in the pH range of 6-9. The detected intermediates were 4-hydroxy-benzaldehyde and 4-methyl-1,2-benzodiol. TOC studies show that 93% of total organic carbon was removed from solution during irradiation time. Reusability shows no significant reduction in photocatalytic performance in photodegrading p-cresol. MDPI 2012 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25222/1/Photocatalytic%20degradation%20of%20p.pdf Abdollahi, Yadollah and Abdullah, Abdul Halim and Zainal, Zulkarnain and Yusof, Nor Azah (2012) Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation. International Journal of Molecular Sciences, 13 (1). pp. 302-315. ISSN 1422-0067; ESSN:1422-0067 http://dx.doi.org/10.3390/ijms13010302 10.3390/ijms13010302
institution UPM IR
collection UPM IR
language English
description Photocatalytic degradation of p-cresol was carried out using ZnO under UV irradiation. The amount of photocatalyst, concentration of p-cresol and pH were studied as variables. The residual concentration and mineralization of p-cresol was monitored using a UV-visible spectrophotometer and total organic carbon (TOC) analyzer, respectively. The intermediates were detected by ultra high pressure liquid chromatography (UPLC). The highest photodegradation of p-cresol was observed at 2.5 g/L of ZnO and 100 ppm of pcresol. P-cresol photocatalytic degradation was favorable in the pH range of 6-9. The detected intermediates were 4-hydroxy-benzaldehyde and 4-methyl-1,2-benzodiol. TOC studies show that 93% of total organic carbon was removed from solution during irradiation time. Reusability shows no significant reduction in photocatalytic performance in photodegrading p-cresol.
format Article
author Abdollahi, Yadollah
Abdullah, Abdul Halim
Zainal, Zulkarnain
Yusof, Nor Azah
spellingShingle Abdollahi, Yadollah
Abdullah, Abdul Halim
Zainal, Zulkarnain
Yusof, Nor Azah
Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation
author_facet Abdollahi, Yadollah
Abdullah, Abdul Halim
Zainal, Zulkarnain
Yusof, Nor Azah
author_sort Abdollahi, Yadollah
title Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation
title_short Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation
title_full Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation
title_fullStr Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation
title_full_unstemmed Photocatalytic degradation of p-Cresol by zinc oxide under UV irradiation
title_sort photocatalytic degradation of p-cresol by zinc oxide under uv irradiation
publisher MDPI
publishDate 2012
url http://psasir.upm.edu.my/id/eprint/25222/1/Photocatalytic%20degradation%20of%20p.pdf
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score 13.4562235