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Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application

The quaternary 56TeO2-24B2O3-(20-x)SiO2-xSm2O3 (x = 0.01, 0.02, 0.03, 0.04 and 0.05 M fraction) glasses were fabricated by using melt quenching method. XRD analysis reveals the amorphous nature of the prepared glass samples. FTIR and deconvolution studies show that Sm2O3 influences the modification...

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Main Authors: Asyikin, A.S., Latif, A.A., Halimah, M.K., Zaid, M.H.M., Kamarudin, M.A., Faznny, M.F., Nazrin, S.N., Zaitizila, I.
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Foilsithe: Elsevier Ltd 2024
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spelling oai:psasir.upm.edu.my:105817 http://psasir.upm.edu.my/id/eprint/105817/ Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application Asyikin, A.S. Latif, A.A. Halimah, M.K. Zaid, M.H.M. Kamarudin, M.A. Faznny, M.F. Nazrin, S.N. Zaitizila, I. The quaternary 56TeO2-24B2O3-(20-x)SiO2-xSm2O3 (x = 0.01, 0.02, 0.03, 0.04 and 0.05 M fraction) glasses were fabricated by using melt quenching method. XRD analysis reveals the amorphous nature of the prepared glass samples. FTIR and deconvolution studies show that Sm2O3 influences the modification of the glass network in the silica borotellurite glass system. The optical band gap and Urbach energy increases and decreases respectively with the addition of Sm2O3 beyond 0.02 M fraction. The overall refractive index of the glass system decreases along with the decrement in polarizability and optical basicity. The synthesized glass samples possess metallization criterion values of 0.30399 to 0.31068 which indicates that the glasses can be used for non-linear applications. The nonlinear behaviour of the fabricated samples which include the nonlinear absorption coefficient, nonlinear refractive index, and third order susceptibility attributed to changes in the glass structure. Silica borotellurite glass doped with 0.05 M fraction of samarium oxide that have 1.01 as the FOM value is advantageous for application in all-optical switching (AOS) devices. Elsevier Ltd 2024-01 Article PeerReviewed Asyikin, A.S. and Latif, A.A. and Halimah, M.K. and Zaid, M.H.M. and Kamarudin, M.A. and Faznny, M.F. and Nazrin, S.N. and Zaitizila, I. (2024) Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application. Optics and Laser Technology, 168. art. no. 109857. pp. 1-10. ISSN 0030-3992; ESSN: 1879-2545 https://www.sciencedirect.com/science/article/pii/S0030399223007508 10.1016/j.optlastec.2023.109857
institution UPM IR
collection UPM IR
description The quaternary 56TeO2-24B2O3-(20-x)SiO2-xSm2O3 (x = 0.01, 0.02, 0.03, 0.04 and 0.05 M fraction) glasses were fabricated by using melt quenching method. XRD analysis reveals the amorphous nature of the prepared glass samples. FTIR and deconvolution studies show that Sm2O3 influences the modification of the glass network in the silica borotellurite glass system. The optical band gap and Urbach energy increases and decreases respectively with the addition of Sm2O3 beyond 0.02 M fraction. The overall refractive index of the glass system decreases along with the decrement in polarizability and optical basicity. The synthesized glass samples possess metallization criterion values of 0.30399 to 0.31068 which indicates that the glasses can be used for non-linear applications. The nonlinear behaviour of the fabricated samples which include the nonlinear absorption coefficient, nonlinear refractive index, and third order susceptibility attributed to changes in the glass structure. Silica borotellurite glass doped with 0.05 M fraction of samarium oxide that have 1.01 as the FOM value is advantageous for application in all-optical switching (AOS) devices.
format Article
author Asyikin, A.S.
Latif, A.A.
Halimah, M.K.
Zaid, M.H.M.
Kamarudin, M.A.
Faznny, M.F.
Nazrin, S.N.
Zaitizila, I.
spellingShingle Asyikin, A.S.
Latif, A.A.
Halimah, M.K.
Zaid, M.H.M.
Kamarudin, M.A.
Faznny, M.F.
Nazrin, S.N.
Zaitizila, I.
Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
author_facet Asyikin, A.S.
Latif, A.A.
Halimah, M.K.
Zaid, M.H.M.
Kamarudin, M.A.
Faznny, M.F.
Nazrin, S.N.
Zaitizila, I.
author_sort Asyikin, A.S.
title Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
title_short Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
title_full Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
title_fullStr Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
title_full_unstemmed Structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
title_sort structural and optical properties of samarium doped silica borotellurite glasses for optical switching application
publisher Elsevier Ltd
publishDate 2024
_version_ 1819301631381995520
score 13.4562235

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