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Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method

In this work, Eu3+/Sm3+ co-doped zinc borosilicate glass was prepared by modified melt-quenching method. The effect of Eu3+/Sm3+ to the structural and optical properties was investigated. The optical band gaps increased from 5.023 to 5.179 eV, and 3.832 to 3.986 eV for both for direct/indirect trans...

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Main Authors: Cheong, Wei Mun, Zaid, Mohd Hafiz Mohd, Yap, Wing Fen, Tan, Sin Tee, Matori, Khamirul Amin, Loh, Zhi Wei, Ismail, Ismayadi, Schmid, Siegbert
Format: Article
Published: Springer 2023
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spelling oai:psasir.upm.edu.my:109264 http://psasir.upm.edu.my/id/eprint/109264/ Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method Cheong, Wei Mun Zaid, Mohd Hafiz Mohd Yap, Wing Fen Tan, Sin Tee Matori, Khamirul Amin Loh, Zhi Wei Ismail, Ismayadi Schmid, Siegbert In this work, Eu3+/Sm3+ co-doped zinc borosilicate glass was prepared by modified melt-quenching method. The effect of Eu3+/Sm3+ to the structural and optical properties was investigated. The optical band gaps increased from 5.023 to 5.179 eV, and 3.832 to 3.986 eV for both for direct/indirect transition. Urbach energy decreases from 0.713 to 0.697 eV, while refractive index also decreases from 2.203 to 2.173 with the progress of doping concentration. The photoluminescence measurement reveals the simultaneous amplification of Sm3+ and Eu3+ emission for the co-doping sample, suggesting a synergistic energy transfer between the two ions. The 1EuSmZBS glass samples show the highest emission intensity. The CIE chromaticity coordinates, CCT, and color purity of the glass sample present high intensity of reddish-orange emission color. In conclusion, Eu3+/Sm3+ co-doped zinc borosilicate glass can lead to enhanced and tunable luminescence properties, and potentially use as a glass host phosphor in optoelectronic applications. Springer 2023-11 Article PeerReviewed Cheong, Wei Mun and Zaid, Mohd Hafiz Mohd and Yap, Wing Fen and Tan, Sin Tee and Matori, Khamirul Amin and Loh, Zhi Wei and Ismail, Ismayadi and Schmid, Siegbert (2023) Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method. Journal of Materials Science: Materials in Electronics, 34 (31). art. no. 2102. -. ISSN 0957-4522; ESSN: 1573-482X https://link.springer.com/article/10.1007/s10854-023-11561-w?error=cookies_not_supported&code=264149f8-b0cf-41e7-b6be-a9b404ab3549 10.1007/s10854-023-11561-w
institution UPM IR
collection UPM IR
description In this work, Eu3+/Sm3+ co-doped zinc borosilicate glass was prepared by modified melt-quenching method. The effect of Eu3+/Sm3+ to the structural and optical properties was investigated. The optical band gaps increased from 5.023 to 5.179 eV, and 3.832 to 3.986 eV for both for direct/indirect transition. Urbach energy decreases from 0.713 to 0.697 eV, while refractive index also decreases from 2.203 to 2.173 with the progress of doping concentration. The photoluminescence measurement reveals the simultaneous amplification of Sm3+ and Eu3+ emission for the co-doping sample, suggesting a synergistic energy transfer between the two ions. The 1EuSmZBS glass samples show the highest emission intensity. The CIE chromaticity coordinates, CCT, and color purity of the glass sample present high intensity of reddish-orange emission color. In conclusion, Eu3+/Sm3+ co-doped zinc borosilicate glass can lead to enhanced and tunable luminescence properties, and potentially use as a glass host phosphor in optoelectronic applications.
format Article
author Cheong, Wei Mun
Zaid, Mohd Hafiz Mohd
Yap, Wing Fen
Tan, Sin Tee
Matori, Khamirul Amin
Loh, Zhi Wei
Ismail, Ismayadi
Schmid, Siegbert
spellingShingle Cheong, Wei Mun
Zaid, Mohd Hafiz Mohd
Yap, Wing Fen
Tan, Sin Tee
Matori, Khamirul Amin
Loh, Zhi Wei
Ismail, Ismayadi
Schmid, Siegbert
Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
author_facet Cheong, Wei Mun
Zaid, Mohd Hafiz Mohd
Yap, Wing Fen
Tan, Sin Tee
Matori, Khamirul Amin
Loh, Zhi Wei
Ismail, Ismayadi
Schmid, Siegbert
author_sort Cheong, Wei Mun
title Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
title_short Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
title_full Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
title_fullStr Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
title_full_unstemmed Structural and optical analysis of Eu3+/Sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
title_sort structural and optical analysis of eu3+/sm3+ co-doped zinc borosilicate glass fabricated by modified melt-quenching method
publisher Springer
publishDate 2023
_version_ 1819301866189619200
score 13.4562235

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