Cover Image

Development of porous MIL-101 derived catalyst application for green diesel production

A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to...

Full description

Saved in:
Bibliographic Details
Main Authors: Chang, He, Seenivasagam, Sivasangar, Taufiq Yap, Yun Hin, Saiman, Mohd Izham, Ghassan, Abdulkareem-Alsultan
Format: Article
Language:English
Published: Elsevier 2023
Subjects:
Biofuel
Online Access:http://psasir.upm.edu.my/id/eprint/111492/1/Development%20of%20porous%20MIL-101%20derived%20c...pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
id oai:psasir.upm.edu.my:111492
record_format eprints
spelling oai:psasir.upm.edu.my:111492 http://psasir.upm.edu.my/id/eprint/111492/ Development of porous MIL-101 derived catalyst application for green diesel production Chang, He Seenivasagam, Sivasangar Taufiq Yap, Yun Hin Saiman, Mohd Izham Ghassan, Abdulkareem-Alsultan A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt% catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 % with Ni loading > 8 wt% on P-MIL-101. In addition, both 25 and 14 wt% Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 % alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. Elsevier 2023 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/111492/1/Development%20of%20porous%20MIL-101%20derived%20c...pdf Chang, He and Seenivasagam, Sivasangar and Taufiq Yap, Yun Hin and Saiman, Mohd Izham and Ghassan, Abdulkareem-Alsultan (2023) Development of porous MIL-101 derived catalyst application for green diesel production. Fuel, 355. art. no. 129459. pp. 1-21. ISSN 0016-2361 https://www.sciencedirect.com/science/article/pii/S0016236123020732 Biofuel 10.1016/j.fuel.2023.129459
institution UPM IR
collection UPM IR
language English
topic Biofuel
spellingShingle Biofuel
Chang, He
Seenivasagam, Sivasangar
Taufiq Yap, Yun Hin
Saiman, Mohd Izham
Ghassan, Abdulkareem-Alsultan
Development of porous MIL-101 derived catalyst application for green diesel production
description A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt% catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 % with Ni loading > 8 wt% on P-MIL-101. In addition, both 25 and 14 wt% Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 % alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production.
format Article
author Chang, He
Seenivasagam, Sivasangar
Taufiq Yap, Yun Hin
Saiman, Mohd Izham
Ghassan, Abdulkareem-Alsultan
author_facet Chang, He
Seenivasagam, Sivasangar
Taufiq Yap, Yun Hin
Saiman, Mohd Izham
Ghassan, Abdulkareem-Alsultan
author_sort Chang, He
title Development of porous MIL-101 derived catalyst application for green diesel production
title_short Development of porous MIL-101 derived catalyst application for green diesel production
title_full Development of porous MIL-101 derived catalyst application for green diesel production
title_fullStr Development of porous MIL-101 derived catalyst application for green diesel production
title_full_unstemmed Development of porous MIL-101 derived catalyst application for green diesel production
title_sort development of porous mil-101 derived catalyst application for green diesel production
publisher Elsevier
publishDate 2023
url http://psasir.upm.edu.my/id/eprint/111492/1/Development%20of%20porous%20MIL-101%20derived%20c...pdf
_version_ 1819301983251595264
score 13.4562235

Similar Items