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Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies

Removing deleterious cationic dyes from wastewater is crucial due to their persistence, toxicity, and harmful effects on public health and ecosystems. In this study, microwaved chitosan nanoparticles (MWCNP) were synthesized and characterized using transmission electron microscopy and Fourier-transf...

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Main Authors: Katibi, Kamil Kayode, Shitu, Ibrahim Garba, Othman, Siti Hajar, Md Yunos, Khairul Faezah, Ismail, Ahmad Fauzi, Noorisma KhairulAqmar, Noordinie Afina, Ilias, Hanis Masyithah
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Published: Springer Nature 2024
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spelling oai:psasir.upm.edu.my:112089 http://psasir.upm.edu.my/id/eprint/112089/ Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies Katibi, Kamil Kayode Shitu, Ibrahim Garba Othman, Siti Hajar Md Yunos, Khairul Faezah Ismail, Ahmad Fauzi Noorisma KhairulAqmar, Noordinie Afina Ilias, Hanis Masyithah Removing deleterious cationic dyes from wastewater is crucial due to their persistence, toxicity, and harmful effects on public health and ecosystems. In this study, microwaved chitosan nanoparticles (MWCNP) were synthesized and characterized using transmission electron microscopy and Fourier-transform infrared spectroscopy to assess their size and functional groups. Then, nascent polyvinylidene fluoride-polyethylene glycol membrane and composite membranes were fabricated with varying MWCNP concentrations (0.3–1.0 wt.%) through the non-solvent phase inversion (NIPs) technique. The resulting membranes underwent analysis for porosity, contact angle, tensile strength, energy dispersive X-ray (EDX), field emission scanning electron microscopy (FESEM), permeate flux, surface zeta potential, fouling resistance, and dye removal. Composite membranes outperformed nascent ones, with the 0.7 wt.% MWCNP composite membrane exhibiting the best performance, having a contact angle of 49.8°, a zeta potential of − 47.4 mV, tensile strength of 2.9 MPa, porosity of 83.7%, methylene blue removal of 96.7%, and permeate flux of 125.3 L.m−2.h−1. The 0.7 wt.% MWCNP composite membrane also showed enhanced antifouling properties after three filtration cycles with an FRR of 80.7% and an RFR of 16.2%. These results demonstrate the efficiency of MWCNP-containing membranes, making them suitable for textile wastewater treatment. © Qatar University and Springer Nature Switzerland AG 2024. Springer Nature 2024 Article PeerReviewed Katibi, Kamil Kayode and Shitu, Ibrahim Garba and Othman, Siti Hajar and Md Yunos, Khairul Faezah and Ismail, Ahmad Fauzi and Noorisma KhairulAqmar, Noordinie Afina and Ilias, Hanis Masyithah (2024) Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies. Emergent Materials, 7 (3). pp. 999-1018. ISSN 2522-5731; ESSN: 2522-574X https://link.springer.com/article/10.1007/s42247-024-00664-7 10.1007/s42247-024-00664-7
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description Removing deleterious cationic dyes from wastewater is crucial due to their persistence, toxicity, and harmful effects on public health and ecosystems. In this study, microwaved chitosan nanoparticles (MWCNP) were synthesized and characterized using transmission electron microscopy and Fourier-transform infrared spectroscopy to assess their size and functional groups. Then, nascent polyvinylidene fluoride-polyethylene glycol membrane and composite membranes were fabricated with varying MWCNP concentrations (0.3–1.0 wt.%) through the non-solvent phase inversion (NIPs) technique. The resulting membranes underwent analysis for porosity, contact angle, tensile strength, energy dispersive X-ray (EDX), field emission scanning electron microscopy (FESEM), permeate flux, surface zeta potential, fouling resistance, and dye removal. Composite membranes outperformed nascent ones, with the 0.7 wt.% MWCNP composite membrane exhibiting the best performance, having a contact angle of 49.8°, a zeta potential of − 47.4 mV, tensile strength of 2.9 MPa, porosity of 83.7%, methylene blue removal of 96.7%, and permeate flux of 125.3 L.m−2.h−1. The 0.7 wt.% MWCNP composite membrane also showed enhanced antifouling properties after three filtration cycles with an FRR of 80.7% and an RFR of 16.2%. These results demonstrate the efficiency of MWCNP-containing membranes, making them suitable for textile wastewater treatment. © Qatar University and Springer Nature Switzerland AG 2024.
format Article
author Katibi, Kamil Kayode
Shitu, Ibrahim Garba
Othman, Siti Hajar
Md Yunos, Khairul Faezah
Ismail, Ahmad Fauzi
Noorisma KhairulAqmar, Noordinie Afina
Ilias, Hanis Masyithah
spellingShingle Katibi, Kamil Kayode
Shitu, Ibrahim Garba
Othman, Siti Hajar
Md Yunos, Khairul Faezah
Ismail, Ahmad Fauzi
Noorisma KhairulAqmar, Noordinie Afina
Ilias, Hanis Masyithah
Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
author_facet Katibi, Kamil Kayode
Shitu, Ibrahim Garba
Othman, Siti Hajar
Md Yunos, Khairul Faezah
Ismail, Ahmad Fauzi
Noorisma KhairulAqmar, Noordinie Afina
Ilias, Hanis Masyithah
author_sort Katibi, Kamil Kayode
title Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
title_short Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
title_full Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
title_fullStr Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
title_full_unstemmed Development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
title_sort development of eco-friendly microwaved chitosan-based nanocomposite membrane for efficient capturing of cationic dyes from aqueous solution: permeability and fouling studies
publisher Springer Nature
publishDate 2024
_version_ 1819302026126819328
score 13.4562235

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