Determination of ethanol concentration of ethanol/water mixture solutions with open ended coaxial method
This study presents a simple and non-destructive procedure to determine ethanol concentration of ethanol/water solution at ambient temperature based on HP85070B open ended coaxial dielectric constant measurement. The motivation for this study stems from the fact that the `true' concentration of...
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| Main Authors: | , , , , |
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
IEEE
2016
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| Online Access: | http://psasir.upm.edu.my/id/eprint/53927/1/Determination%20of%20ethanol%20concentration%20of.pdf |
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| Summary: | This study presents a simple and non-destructive procedure to determine ethanol concentration of ethanol/water solution at ambient temperature based on HP85070B open ended coaxial dielectric constant measurement. The motivation for this study stems from the fact that the `true' concentration of ethanol in a `labeled' container could be `spoiled' due to hygroscopic nature of ethanol, evaporation and other factors. The dielectric constant measurements of eight samples with different molar fraction were validated with modified Cole-Cole-Debye (3CC) simulations. A 5th degree polynomial calibration equation was developed based on 3CC simulations with R2 = 0.9998 and used to estimate the `true' concentration of three ethanol samples obtained from `labeled' containers kept in laboratory. The ethanol concentrations of two of the samples were found to be much lower than what was indicated on their labels, hence, assumed spoiled. |
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