Omslagsbillede

Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol

In this work, several copper supported catalysts, Cu/Dol, Cu/Al2O3, Cu/Bent, Cu/Mont, and Cu/Talc were prepared using wet impregnation route and characterized using BET, BJH, XRD, H2-TPR, NH3–TPD, and SEM analytical techniques and subsequently tested in hydrogenolysis of glycerol to 1,2-propanediol...

Fuld beskrivelse

Saved in:
Bibliografiske detaljer
Main Authors: Azri, Norsahida, Ramli, Irmawati, Usman Idris, Nda-Umar, Saiman, Mohd Izham, Yap, Taufiq Yun Hin
Format: Article
Sprog:English
Udgivet: Elsevier 2021
Online adgang:http://psasir.upm.edu.my/id/eprint/96877/1/ABSTRACT.pdf
Tags: Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!
id oai:psasir.upm.edu.my:96877
record_format eprints
spelling oai:psasir.upm.edu.my:96877 http://psasir.upm.edu.my/id/eprint/96877/ Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol Azri, Norsahida Ramli, Irmawati Usman Idris, Nda-Umar Saiman, Mohd Izham Yap, Taufiq Yun Hin In this work, several copper supported catalysts, Cu/Dol, Cu/Al2O3, Cu/Bent, Cu/Mont, and Cu/Talc were prepared using wet impregnation route and characterized using BET, BJH, XRD, H2-TPR, NH3–TPD, and SEM analytical techniques and subsequently tested in hydrogenolysis of glycerol to 1,2-propanediol (1,2-PDO). The nature of support was found to determine the activation of the catalysts. Among the tested catalysts, dolomite supported copper catalyst (Cu/Dol) exhibited superior performance due to the copper and dolomite species mutual interaction. The findings from the various characterization tests showed that the presence of copper species were essentially enriched on the dolomite grain surfaces, the redox properties, and acidic property of the catalyst enhanced, as well as the formation of the small size of the catalyst (Cu/Dol) contributed to the high conversion of glycerol (78.5%) and high 1,2-PDO selectivity (79%) with low methanol production as the by-product at 200 °C, 4 MPa H2 and 10 h reaction conditions. Elsevier 2021 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/96877/1/ABSTRACT.pdf Azri, Norsahida and Ramli, Irmawati and Usman Idris, Nda-Umar and Saiman, Mohd Izham and Yap, Taufiq Yun Hin (2021) Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol. Journal of King Saud University, 33 (4). art. no. 101417. pp. 1-21. ISSN 1018-3647 https://www.sciencedirect.com/science/article/pii/S1018364721000781 10.1016/j.jksus.2021.101417
institution UPM IR
collection UPM IR
language English
description In this work, several copper supported catalysts, Cu/Dol, Cu/Al2O3, Cu/Bent, Cu/Mont, and Cu/Talc were prepared using wet impregnation route and characterized using BET, BJH, XRD, H2-TPR, NH3–TPD, and SEM analytical techniques and subsequently tested in hydrogenolysis of glycerol to 1,2-propanediol (1,2-PDO). The nature of support was found to determine the activation of the catalysts. Among the tested catalysts, dolomite supported copper catalyst (Cu/Dol) exhibited superior performance due to the copper and dolomite species mutual interaction. The findings from the various characterization tests showed that the presence of copper species were essentially enriched on the dolomite grain surfaces, the redox properties, and acidic property of the catalyst enhanced, as well as the formation of the small size of the catalyst (Cu/Dol) contributed to the high conversion of glycerol (78.5%) and high 1,2-PDO selectivity (79%) with low methanol production as the by-product at 200 °C, 4 MPa H2 and 10 h reaction conditions.
format Article
author Azri, Norsahida
Ramli, Irmawati
Usman Idris, Nda-Umar
Saiman, Mohd Izham
Yap, Taufiq Yun Hin
spellingShingle Azri, Norsahida
Ramli, Irmawati
Usman Idris, Nda-Umar
Saiman, Mohd Izham
Yap, Taufiq Yun Hin
Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
author_facet Azri, Norsahida
Ramli, Irmawati
Usman Idris, Nda-Umar
Saiman, Mohd Izham
Yap, Taufiq Yun Hin
author_sort Azri, Norsahida
title Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
title_short Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
title_full Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
title_fullStr Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
title_full_unstemmed Effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
title_sort effect of different supports for copper as catalysts on glycerol hydrogenolysis to 1,2-propanediol
publisher Elsevier
publishDate 2021
url http://psasir.upm.edu.my/id/eprint/96877/1/ABSTRACT.pdf
_version_ 1819300887090167808
score 13.4562235

Lignende værker